List of participating institutions - EMEP-CCC-Report-1-2021.pdf (6.539Mb)

Armenia Environmental Monitoring and Information Center

Austria Umweltbundesamt

Belarus Institute Nature Management

Belgium Belgian Interregional Environment Agency (IRCEL - CELINE) Flanders Environment Agency

Commission of the

European Communities Joint Research Center, EC-JRC

Croatia Croation Meteorological and Hydrological Service Cyprus Ministry of Labour, Welfare and Social Insurance Czech Republic Czech Hydrometeorological Institute

Denmark Department of Environmental Science, Aarhus Universityf Estonia Estonian Environmental Research Centre

Finland Finnish Meteorological Institute (FMI)

France Mines Douai

Georgia National Environmental Agency

Germany Umweltbundesamt

Leibniz Institute for Tropospheric Research Greece Hellenic Ministry of the Environment and Energy

University of Crete

Hungary Hungarian Meteorological Service

Iceland Vedurstofa Islands

Ireland Met Eireann

Italy CNR–ISAC

Arpa Umbria

Latvia Latvian Environment, Geology and Meteorology Agency Lithuania SRI Center for Physical Sciences and Technology Macedonia Ministry of Environment and Physical Planning Malta Department of Geoscience, University of Malta

Moldova Environmental Agency

Montenegro Institute of Hydrometeorology and Seismology

The Netherlands National Institute for Public Health and the Environment (RIVM) Norway Norwegian Institute for Air Research (NILU)

Poland Institute of Meteorology and Water Management Institute of Environmental Protection

Russian Federation Institute of Global Climate and Ecology Serbia Environmental Protection Agency Slovakia Slovak Hydrometeorological Institute Slovenia Slovenian Environment Agency

Spain Ministerio para la Transicion Ecologica, Agencia Estatal de Meteorologica

Sweden Swedish Environmental Research Institute (IVL)

Switzerland Swiss Federal Laboratories for Materials Science and Technology (EMPA)

United Kingdom Ricardo-AEA

Annex 1

Maps over Europe

Figure 1.1: Geographical distribution of sulphur dioxide 2019. Unit:  g S/m

.

Figure 1.3: Geographical distribution of sulphate in aerosols 2019. Unit:  g S/m

.

Figure 1.5: Geographical distribution of PM

2.5

2019. Unit:  g/m

.

Figure 1.7: Geographical distribution of ammonium in precipitation 2019.

Unit: mg N/l.

Figure 1.9: Geographical distribution of excess sulphate in precipitation 2019. Unit: mg

S/l.

Figure 1.11: Geographical distribution of OC in PM

2019. Unit: µg C/m

.

Figure 1.13: Geographical distribution of EC in PM

2019. Unit: µg C/m

.

Annex 2

Annual statistics on precipitation data

AM0001R Amberd

CH0005R Rigi

DE0002R Waldhof

DE0009R Zingst

DK0022R Sepstrup Sande

ES0005R Noia

ES0009R Campisabalos

ES0014R Els Torms

FI0022R Oulanka

FR0009R Revin

FR0015R La Tardière

GB0002R Eskdalemuir

GB0015R Strath Vaich Dam

HR0004R Zavizan January 2019 - December 2019

W. Min Max Dep % Num Num Component matrix mean anal bel sampl Ca++ precip 0.83 0.12 16.47 1591.8 99.6 0 124 Cl- precip 1.15 0.11 16.56 2210.2 99.6 0 124 K+ precip 0.43 0.11 2.29 828.2 99.6 0 124 Mg++ precip 0.43 0.11 1.22 818.9 99.6 0 124 NH4+ precip 0.41 0.10 2.36 785.8 99.6 0 124 NO3- precip 0.44 0.11 2.69 841.4 99.6 0 124 Na+ precip 0.75 0.11 7.93 1434.9 99.6 0 124 Precip off precip - 0.00 95.20 1917.4 100.0 0 365 SO4-- precip 0.43 0.11 2.82 829.2 99.6 0 124 SO4-- corr precip 0.37 -0.21 2.36 708.3 99.6 0 124 cond precip 11.22 1.00 135.20 21512.0 99.6 0 124 pH precip 5.63 4.65 7.72 4465.9 99.6 0 124

HU0002R K-puszta January 2019 - December 2019

W. Min Max Dep % Num Num Component matrix mean anal bel sampl Ca++ precip 0.47 0.01 16.62 280.0 91.4 1 76 Cl- precip 0.84 0.07 6.67 497.6 93.4 0 81 K+ precip 0.17 0.02 0.86 97.9 91.4 10 76 Mg++ precip 0.10 0.01 1.24 59.3 91.4 1 76 NH4+ precip 0.52 0.02 3.85 310.7 81.5 0 76 NO3- precip 0.30 0.01 1.90 177.9 93.4 2 81 Na+ precip 1.20 0.03 6.95 712.6 91.4 1 76 Precip precip - 0.00 35.50 593.1 100.0 0 366 Precip off precip - 0.00 33.80 555.6 100.0 0 366 SO4-- precip 0.48 0.01 5.26 286.7 92.7 2 80 SO4-- corr precip 0.42 -0.04 4.86 250.8 92.7 2 80 cond precip 17.17 7.00 151.00 10182.4 93.4 0 85 pH precip 5.62 4.70 7.60 1424.6 93.4 0 81

IE0001R Valentia Observatory January 2019 - December 2019

W. Min Max Dep % Num Num Component matrix mean anal bel sampl Ca++ precip 0.25 0.03 4.01 389.9 99.2 19 185 Cl- precip 9.14 0.14 129.14 14348.5 99.2 0 185 K+ precip 0.23 0.03 3.91 359.1 99.2 37 185 Mg++ precip 0.65 0.03 11.59 1013.3 99.2 10 185 NH4+ precip 0.11 0.02 18.49 175.5 99.1 129 184 NO3- precip 0.05 0.01 1.15 79.1 99.2 31 186 Na+ precip 5.29 0.06 95.38 8310.0 99.2 0 185 Precip precip - 0.00 36.00 1570.7 87.7 0 321 Precip off precip - 0.00 37.00 1701.4 100.0 0 366 SO4-- precip 0.50 0.01 8.68 792.3 99.2 1 185 SO4-- corr precip 0.06 -0.12 1.84 97.0 99.2 1 185 cond precip 40.14 2.30 620.00 63042.6 99.2 0 185 pH precip 5.33 4.68 7.78 7397.9 99.2 0 185

IE0005R Oak Park

IS0091R Storhofdi

NL0091R De Zilk

NO0056R Hurdal January 2019 - December 2019

W. Min Max Dep % Num Num Component matrix mean anal bel sampl Ca++ precip 0.13 0.01 2.79 165.7 99.6 0 134 Cl- precip 0.26 0.01 2.54 328.5 99.6 2 134 K+ precip 0.10 0.01 1.50 125.8 98.4 7 131 Mg++ precip 0.03 0.01 0.32 34.3 99.6 23 134 NH4+ precip 0.20 0.01 3.97 258.2 98.4 8 131 NO3- precip 0.20 0.01 3.04 254.0 99.6 2 134 Na+ precip 0.15 0.01 1.67 185.7 99.6 2 134 Precip precip - 0.00 58.90 1260.4 100.0 0 366 SO4-- precip 0.16 0.01 2.79 196.8 99.6 1 134 SO4-- corr precip 0.14 0.01 2.71 181.2 99.6 1 134 cond precip 7.78 2.00 67.00 9801.3 99.5 0 132 pH precip 5.12 4.24 6.19 9642.4 98.3 0 129

PL0002R Jarczew January 2019 - December 2019

W. Min Max Dep % Num Num Component matrix mean anal bel sampl Ca++ precip 0.29 0.02 4.41 147.2 99.3 0 99 Cl- precip 0.31 0.06 3.79 154.5 99.3 0 99 K+ precip 0.14 0.02 1.69 68.9 99.3 0 99 Mg++ precip 0.06 0.01 0.38 28.0 99.3 0 99 NH4+ precip 0.46 0.12 3.27 228.6 99.3 0 99 NO3- precip 0.36 0.12 1.90 178.3 99.3 0 99 Na+ precip 0.15 0.02 2.11 76.1 99.3 0 99 Precip precip - 0.00 37.90 501.2 96.7 0 354 Precip off precip - 0.00 37.60 510.2 96.7 0 354 SO4-- precip 0.42 0.11 4.37 209.6 99.3 0 99 SO4-- corr precip 0.41 0.10 4.25 203.0 99.3 0 99 cond precip 11.36 4.00 67.00 5695.2 99.3 0 99 pH precip 5.28 4.20 7.11 2619.3 99.3 0 99

PL0003R Sniezka January 2019 - December 2019

W. Min Max Dep % Num Num Component matrix mean anal bel sampl Ca++ precip 0.67 0.02 18.79 449.6 100.0 0 155 Cl- precip 0.77 0.06 14.39 518.7 100.0 0 155 K+ precip 0.35 0.01 3.51 237.3 100.0 0 155 Mg++ precip 0.17 0.00 3.39 111.9 100.0 0 155 NH4+ precip 0.48 0.03 7.31 324.6 100.0 0 155 NO3- precip 1.04 0.17 18.27 697.7 100.0 0 155 Na+ precip 0.89 0.01 17.00 596.8 100.0 0 155 Precip precip - 0.00 30.90 671.8 89.9 0 329 Precip off precip - 0.00 44.90 1072.8 89.9 0 329 SO4-- precip 1.03 0.15 9.92 693.5 100.0 0 155 SO4-- corr precip 0.98 0.15 9.19 655.6 100.0 0 155 cond precip 30.86 10.00 305.00 20730.5 100.0 0 155 pH precip 4.50 4.18 4.72 21030.4 100.0 0 155

PL0004R Leba

RU0018R Danki

SE0020R Hallahus

SK0004R Stará Lesná January 2019 - December 2019

W. Min Max Dep % Num Num Component matrix mean anal bel sampl Ca++ precip 0.28 0.04 1.95 199.8 88.4 0 29 Cl- precip 0.17 0.06 1.28 122.5 88.4 0 29 K+ precip 0.13 0.02 0.86 95.6 88.4 0 29 Mg++ precip 0.04 0.01 0.16 26.9 88.4 0 29 NH4+ precip 0.76 0.03 4.35 553.9 88.4 0 29 NO3- precip 0.22 0.09 0.81 162.0 88.4 0 29 Na+ precip 0.31 0.03 8.95 227.0 88.4 0 29 Precip precip - 0.00 95.50 724.7 86.1 0 45 SO4-- precip 0.41 0.12 3.75 297.0 88.4 0 29 SO4-- corr precip 0.40 0.12 3.69 287.9 88.4 0 29 cond precip 13.97 4.96 54.63 10122.9 81.8 0 21 pH precip 6.12 5.13 6.94 544.7 81.8 0 21

SK0006R Starina January 2019 - December 2019

W. Min Max Dep % Num Num Component matrix mean anal bel sampl Ca++ precip 0.22 0.02 0.74 95.1 95.1 0 77 Cl- precip 0.20 0.02 1.54 84.4 95.1 4 77 K+ precip 0.12 0.01 0.97 50.4 95.1 0 77 Mg++ precip 0.03 0.01 0.15 11.9 95.1 0 77 NH4+ precip 0.43 0.01 2.25 183.0 95.1 0 77 NO3- precip 0.32 0.07 1.35 135.3 95.1 0 77 Na+ precip 0.35 0.02 5.65 148.5 95.1 4 77 Precip precip - 0.00 43.80 425.3 100.0 0 366 SO4-- precip 0.46 0.09 1.52 194.6 95.1 0 77 SO4-- corr precip 0.44 0.08 1.52 188.7 95.1 0 77 cond precip 13.44 5.71 43.97 5716.5 81.8 0 48 pH precip 5.30 4.68 6.48 2114.3 81.8 0 48

SK0007R Topolniky January 2019 - December 2019

W. Min Max Dep % Num Num Component matrix mean anal bel sampl Ca++ precip 0.27 0.02 4.09 132.8 98.8 0 33 Cl- precip 0.18 0.07 0.89 88.2 98.8 0 33 K+ precip 0.05 0.00 0.27 23.0 99.3 0 34 Mg++ precip 0.03 0.00 0.35 15.9 98.8 0 33 NH4+ precip 0.48 0.06 1.78 234.1 98.8 0 33 NO3- precip 0.29 0.11 0.83 139.3 98.8 0 33 Na+ precip 0.26 0.04 1.76 124.3 98.8 0 33 Precip precip - 0.00 38.50 483.0 99.3 0 53 SO4-- precip 0.39 0.10 1.61 187.0 98.8 0 33 SO4-- corr precip 0.37 0.09 1.51 180.3 98.8 0 33 cond precip 10.87 4.91 41.67 5249.9 90.1 0 25 pH precip 5.42 4.46 6.52 1840.3 90.1 0 25

Annex 3

Annual statistics on particulate mass and inorganics

in air and aerosols

AM0001R Amberd

BE0013R Houtem

CH0005R Rigi

CZ0005R Churanov

DE0007R Neuglobsow

DE0054R Zugspitze-Schneefernerhaus

DK0012R Risoe

ES0001R San Pablo de los Montes

ES0007R Víznar

ES0009R Campisabalos

ES0013R Penausende

ES1778R Montseny

FI0022R Oulanka

FR0008R Donon

FR0018R La Coulonche

GB0006R Lough Navar

GB0045R Wicken Fen

GB1055R Chilbolton Observatory

IE0005R Oak Park

IT0004R Ispra

MK0007R Lazaropole

NL0644R Cabauw Wielsekade

NO0039R Kårvatn

PL0003R Sniezka

RU0018R Danki

SE0022R Norunda Stenen

SK0006R Starina January 2019 - December 2019

Arit Arit Geom Geom Min 5% 50% 95% Max % Num Num Component matrix mean sd mean sd anal bel sampl Ca++ aerosol 0.28 0.23 0.21 2.20 0.01 0.07 0.23 0.70 1.94 98 7 360 Cl- aerosol 0.59 0.57 0.44 2.14 0.04 0.12 0.46 1.45 6.16 99 0 365 HNO3 air 0.06 0.09 0.04 2.41 0.01 0.01 0.04 0.19 0.98 98 0 361 K+ aerosol 0.01 0.01 0.01 1.65 0.01 0.01 0.01 0.03 0.08 99 263 364 Mg++ aerosol 0.05 0.08 0.03 2.07 0.01 0.02 0.02 0.14 1.20 99 199 365 NH3 air 0.28 0.20 0.23 2.02 0.01 0.08 0.24 0.66 1.64 99 3 364 NH4+ aerosol 0.14 0.19 0.10 2.40 0.01 0.02 0.10 0.35 1.73 99 14 365 NO2 air 1.04 0.74 0.82 2.31 0.01 0.24 0.93 2.23 7.61 98 6 362 NO3- aerosol 0.44 0.51 0.29 2.56 0.00 0.07 0.29 1.40 4.46 98 3 360 Na+ aerosol 0.05 0.05 0.03 2.41 0.01 0.01 0.04 0.12 0.43 99 103 365 SO2 air 0.61 0.94 0.36 2.67 0.01 0.07 0.36 2.01 11.40 98 0 360 SO4-- aerosol 0.83 0.67 0.60 2.44 0.00 0.14 0.63 2.22 4.08 98 1 360 SO4-- corr aerosol 0.81 0.66 0.60 2.43 -0.01 0.13 0.62 2.21 4.07 98 1 360

SK0007R Topolniky January 2019 - December 2019

Arit Arit Geom Geom Min 5% 50% 95% Max % Num Num Component matrix mean sd mean sd anal bel sampl PM10 mass pm10 21.36 8.78 19.99 1.50 9.83 10.16 20.00 38.42 42.87 90 0 49

Annex 4

Annual statistics on carbonaceous compounds

CH0002R Payerne

DE0007R Neuglobsow

ES0012R Zarra

FR0013R Peyrusse Vieille

FR0025R Verneuil

NO0056R Hurdal January 2019 - December 2019

Arit Arit Geom Geom Min 5% 50% 95% Max % Num Num Component matrix mean sd mean sd anal bel sampl EC pm10 0.10 0.06 0.09 1.63 0.03 0.05 0.08 0.24 0.39 98 0 52 OC pm10 1.23 0.92 0.94 2.07 0.28 0.30 0.91 3.35 4.30 98 0 52 TC pm10 1.34 0.95 1.05 1.97 0.34 0.35 1.02 3.45 4.69 98 0 52 EC pm25 0.09 0.07 0.08 1.73 0.03 0.04 0.08 0.25 0.40 98 0 52 OC pm25 0.71 0.55 0.58 1.79 0.23 0.25 0.56 1.63 3.52 98 0 52 TC pm25 0.81 0.60 0.67 1.75 0.27 0.30 0.65 1.88 3.92 98 0 52 OC pm10_pm25 0.52 0.64 0.25 4.28 0.00 0.00 0.20 2.17 2.57 98 3 52 TC pm10_pm25 0.53 0.65 0.26 4.21 0.00 0.00 0.21 2.22 2.58 98 3 52

PL0005R Diabla Gora January 2019 - December 2019

Arit Arit Geom Geom Min 5% 50% 95% Max % Num Num Component matrix mean sd mean sd anal bel sampl EC pm25 0.39 0.31 0.28 2.39 0.01 0.06 0.28 1.00 1.66 99 0 364 OC pm25 2.73 1.89 2.18 1.99 0.21 0.68 2.25 6.77 10.99 99 0 364 TC pm25 3.12 2.16 2.50 1.97 0.33 0.83 2.54 7.71 11.94 99 0 364

PL0009R Zielonka January 2019 - December 2019

Arit Arit Geom Geom Min 5% 50% 95% Max % Num Num Component matrix mean sd mean sd anal bel sampl EC pm25 0.34 0.25 0.27 2.08 0.04 0.07 0.28 0.91 1.43 48 0 176 OC pm25 3.38 1.79 3.01 1.61 1.11 1.47 3.02 7.48 11.01 48 0 176 TC pm25 3.72 1.99 3.31 1.61 1.19 1.66 3.21 8.03 11.95 48 0 176

SE0022R Norunda Stenen January 2019 - December 2019

Arit Arit Geom Geom Min 5% 50% 95% Max % Num Num Component matrix mean sd mean sd anal bel sampl EC pm10 0.09 0.08 0.07 1.95 0.02 0.03 0.07 0.25 0.55 95 0 118 OC pm10 1.16 0.85 0.89 2.08 0.18 0.26 1.00 2.85 4.68 95 1 118 OC,Artifact=neg pm10 0.16 0.10 0.14 1.74 0.05 0.06 0.13 0.38 0.64 95 0 118 OC,Artifact=pos pm10 0.04 0.03 0.03 1.98 0.01 0.01 0.03 0.09 0.15 95 0 118 OC,Fraction=OC1 pm10 0.07 0.06 0.06 1.92 0.01 0.02 0.05 0.20 0.40 95 0 118 OC,Fraction=OC2 pm10 0.17 0.14 0.13 2.10 0.02 0.04 0.13 0.46 0.80 95 0 118 OC,Fraction=OC3 pm10 0.41 0.30 0.30 2.25 0.07 0.08 0.36 1.01 1.53 95 0 118 OC,Fraction=OC4 pm10 0.22 0.11 0.19 1.76 0.05 0.07 0.22 0.45 0.56 95 0 118 OC,Fraction=OCPyr pm10 0.29 0.33 0.16 3.16 -0.01 0.02 0.16 1.01 2.19 95 0 118 TC pm10 1.41 0.98 1.13 1.94 0.26 0.41 1.18 3.52 5.32 95 0 118

Annex 5

Overview of sampling and analytical methods 2019

Country: Armenia Main components- EMEP Year: 2019

Station Sampling Sampling

frequency Analysis method Precipitation

Precipitation amount

every event pH meter

Air

Sulphur dioxide AM0001R KOH-impregnated Whatman 40 filter 20–25 m

/day (Filterpack) Daily Ion chromatography

Nitrogen dioxide AM0001R NaI-impregnated glass sinters, 0.6 m

/day Daily Spectrophotometric, Griess method Nitric acid AM0001R KOH-impregnated Whatman 40 filter 20–25 m

/day (Filterpack) Daily Ion chromatography

Ammonia AM0001R Oxalic acid-impregnated Whatman 40 filter, 20–25 m

/day (Filterpack) Daily Spectrophotometric, Nessler method Sulphate AM0001R Teflon filter, Pall Zefluor 2 µm, 47 mm diameter, 20–25 m

/day (Filterpack) Daily Ion chromatography

Nitrate AM0001R Teflon filter, Pall Zefluor 2 µm, 47 mm diameter, 20–25 m

/day (Filterpack) Daily Ion chromatography

Ammonium AM0001R Teflon filter, Pall Zefluor 2 µm, 47 mm diameter, 20–25 m

/day (Filterpack) Daily Spectrophotometric, Nessler method Sodium AM0001R Teflon filter, Pall Zefluor 2 µm, 47 mm diameter, 20–25 m

/day (Filterpack) Daily ICP-MS

Calcium AM0001R Teflon filter, Pall Zefluor 2 µm, 47 mm diameter, 20–25 m

/day (Filterpack) Daily ICP-MS Magnesium AM0001R Teflon filter, Pall Zefluor 2 µm, 47 mm diameter, 20–25 m

/day (Filterpack) Daily ICP-MS Potassium AM0001R Teflon filter, Pall Zefluor 2 µm, 47 mm diameter, 20–25 m

/day (Filterpack) Daily ICP-MS

Chloride AM0001R Teflon filter, Pall Zefluor 2 µm, 47 mm diameter, 20–25 m

/day (Filterpack) Daily Ion chromatography PM

PM

2.5

PM

Sum of nitric acid and nitrate AM0001R KOH-impregnated Whatman 40 filter + Teflon filter, 20–25 m

/day Daily Ion chromatography

Sum of ammonia and ammonium AM0001R Oxalic acid-impregnated Whatman 40 filter +Teflon filter, 20–25 m

/day Daily Spectrophotometric, Nessler method

Country: Austria Main components EMEP Year: 2019

Station Sampling Sampling frequency Analysis method

Precipitation

Precipitation amount

Precipitation amount, official gauge Sulphate

Nitrate Ammonium Magnesium Sodium Chloride Calcium Potassium Conductivity pH

Air

Sulphur dioxide All Instrumental: UV-fluorescence Hourly UV-fluorescence

Sulphur dioxide

Nitrogen dioxide All Instrumental: Chemiluminescence Hourly Chemiluminescence

Nitric acid Ammonia Sulphate Nitrate Ammonium Sodium Calcium Magnesium Potassium Chloride

PM

AT02

AT05, AT48 High Volume Sampler, glass fibre filters with organic binder, 720 m

/day, EN 12341

High Volume Sampler, glass fibre filters with organic binder, 720 m

/day, EN 12341 Daily

Every 3

^rd

day Micro balance PM

2.5

AT02 High Volume Sampler, glass fibre filters with organic binder, 720 m

/day, EN 14907 Daily Micro balance PM

AT02 High Volume Sampler, glass fibre filters with organic binder, 720 m

/day, weighing acc. EN 12341 Every 3

^rd

day Micro balance Sum of nitric acid and nitrate

Sum of ammonia and ammonium

Country: Belarus Main components - EMEP Year: 2019

Station Sampling Sampling frequency Analysis method

Precipitation

Precipitation amount Bulk

Precipitation amount, official gauge

Sulphate Bulk Daily Turbidimetry

Nitrate Bulk Daily Photometry

Ammonium Bulk Daily Photometry with Nessler reactive

Magnesium Bulk Daily AAS

Sodium Bulk Daily AAS

Chloride Bulk Daily Mercurimetric

Calcium Bulk Daily AAS

Potassium Bulk Daily AAS

Conductivity Bulk Daily Conductivity meter

pH Bulk Daily pH meter

Air

Sulphur dioxide Sulphur dioxide Nitrogen dioxide Nitric acid Ammonia Sulphate Nitrate Ammonium Sodium Calcium Magnesium Potassium Chloride PM

PM

2.5

Sum of nitric acid and nitrate

Sum of ammonia and ammonium

Country: Belgium Main components - EMEP Year: 2019

Station Sampling Sampling frequency Analysis method

Precipitation

Precipitation amount BE0014R Wet-only sampler 2 weeks

Precipitation amount, official

gauge BE0014R precipitation gauge

Sulphate BE0014R Wet-only sampler 2 weeks ion chromatography

Nitrate BE0014R Wet-only sampler 2 weeks ion chromatography

Ammonium BE0014R Wet-only sampler 2 weeks ion chromatography

Magnesium BE0014R Wet-only sampler 2 weeks ICP-AES

Sodium BE0014R Wet-only sampler 2 weeks ICP-AES

Chloride BE0014R Wet-only sampler 2 weeks ion chromatography

Calcium BE0014R Wet-only sampler 2 weeks ICP-AES

Potassium BE0014R Wet-only sampler 2 weeks ICP-AES

Conductivity BE0014R Wet-only sampler 2 weeks Conductivity probe

pH BE0014R Wet-only sampler 2 weeks Combined glass electrode

Acidity Air

Sulphur dioxide Instrumental: UV-fluorescence Half hourly UV-fluorescence

Nitrogen dioxide BE0013R,

BE0011R Instrumental: Chemiluminescence Half hourly Chemiluminescence

Nitric acid

Ammonia BE0014R Passive sampler 4 weeks ion chromatography

Sulphate Nitrate Ammonium Sodium Calcium Magnesium Potassium Chloride PM

PM

2.5

PM

Sum of nitric acid and nitrate

Sum of ammonia and ammonium

Country: Croatia Main components - EMEP Year: 2019

Station Sampling Sampling frequency Analysis method

Precipitation

Precipitation amount All

Precipitation amount, official gauge Rain gauge Daily

Sulphate All Bulk Daily Ion chromatography

Nitrate All Bulk Daily Ion chromatography

Ammonium All Bulk Daily Ion chromatography

Magnesium All Bulk Daily Ion chromatography

Sodium All Bulk Daily Ion chromatography

Chloride All Bulk Daily Ion chromatography

Calcium All Bulk Daily Ion chromatography

Potassium All Bulk Daily Ion chromatography

Conductivity All Bulk Daily Conductivity meter

pH All Bulk Daily pH meter

Air

Sulphur dioxide Nitrogen dioxide Nitric acid Ammonia Sulphate Nitrate Ammonium Sodium Calcium Magnesium Potassium Chloride PM

PM

2.5

Sum of nitric acid and nitrate

Sum of ammonia and ammonium

Country: Cyprus Main components - EMEP Year: 2019

Station Sampling Sampling frequency Analysis method

Precipitation Precipitation amount

Precipitation amount, official gauge Sulphate

Nitrate Ammonium Magnesium Sodium Chloride Calcium Potassium Conductivity pH Air

Sulphur dioxide CY02 Instrumental: UV-fluorescence Hourly UV-fluorescence

Nitrogen dioxide CY02 Instrumental: Chemiluminescence Hourly Chemiluminescence

Nitric acid Ammonia

CY02 Low volume sampler Daily Ion Chromatography

PM

CY02 High volume sampler Daily Gravimetric

PM

2.5

CY02 Low volume sampler Daily Gravimetric

PM

OC/EC in PM2,5 CY02 Low volume sampler Daily

OC EC Lab Instrument, Model 5

Sunset Laboratory Inc.

Country: Czech Republic Main components - EMEP Year: 2019

Station Sampling Sampling frequency Analysis method

Precipitation

Precipitation amount, official gauge All Meteorological Station Daily Automatically gauge

Fluoride All Wet-only (daily) at CZ03, (weekly) at CZ05 Daily, weekly Ion Chromatography

Sulphate All Wet-only (daily) at CZ03, (weekly) at CZ05 Daily, weekly Ion chromatography

Nitrate All Wet-only (daily) at CZ03, (weekly) at CZ05 Daily, weekly Ion chromatography

Ammonium All Wet-only (daily) at CZ03, (weekly) at CZ05 Daily, weekly Spectrophotometric, Indophenol method, FIA-Berth

Magnesium All Wet-only (daily) at CZ03, (weekly) at CZ05 Daily, weekly F-AAS

Sodium All Wet-only (daily) at CZ03, (weekly) at CZ05 Daily, weekly F-AAS

Chloride All Wet-only (daily) at CZ03, (weekly) at CZ05 Daily, weekly Ion chromatography

Calcium All Wet-only (daily) at CZ03, (weekly) at CZ05 Daily, weekly F-AAS

Potassium All Wet-only (daily) at CZ03, (weekly) at CZ05 Daily, weekly F-AAS

Conductivity All Wet-only (daily) at CZ03, (weekly) at CZ05 Daily, weekly Conductivity electrode

pH All Wet-only (daily) at CZ03, (weekly) at CZ05 Daily, weekly pH electrode

Air

Sulphur dioxide CZ3,CZ5 KOH-impregnated Whatman 40 filter 47 mm, 20 m

/day Daily, CZ5

indicative(6days) Ion chromatography

Sulphur dioxide CZ3 UV-fluorescence - monitor Hourly UV-fluorescence

Carbon monoxide CZ3 IR corel. absorption spectrometry Hourly IRABS, corel. absorption spectrometry

Nitrogen dioxide CZ3 Chemiluminescence - monitor Hourly Chemiluminescence

Nitrogen monoxide CZ3 Chemiluminescence - monitor Hourly Chemiluminescence

Sum of nitric acid and nitrate CZ3,CZ5 Whatman filter + KOH-impregnated Whatman 40 filter 47 mm,

20 m

/day Daily, CZ5

indicative(6days) Ion Chromatography Sum of ammonia and ammonium CZ3,CZ5 Whatman filter + Citric acid impregnated Whatman 40 filter 47

mm, 20 m

/day Daily, CZ5

indicative(6days) Spectrophotometric, Indophenol method, FIA-Berth

Sulphate CZ3,CZ5 Whatman 40, filter 47 mm, 20 m

/day Daily, CZ5

indicative(6days) Ion chromatography

Sodium CZ3 Filter 47 mm, 55 m

/day Weekly Ion chromatography

Calcium CZ3 Filter 47 mm, 55 m

/day Weekly Ion chromatography

Magnesium CZ3 Filter 47 mm, 55 m

/day Weekly Ion chromatography

Potassium CZ3 Filter 47 mm, 55 m

/day Weekly Ion chromatography

PM

CZ3,CZ5 Filter 47 mm, 55 m

/day Every 2

^nd

day Gravimetry

PM

CZ3 Beta absorption - monitor Hourly Radiometry – beta absorption

PM

2,5

CZ3 Beta absorption - monitor Hourly Radiometry – beta absorption

PM

2.5

CZ3 Filter 47 mm, 55 m

/day Every 2

^nd

day Gravimetry

OC, EC in PM

2.5

CZ3 Filter 47 mm, 24 m

/day Every 6

^th

day HD-FID (Thermal-optical method)

Country: Denmark Main components and ozone - EMEP Year: 2018 - delivery

Station Sampling Sampling

frequency Analysis method

Precipitation

Precipitation amount DK05, DK08, DK12, DK22 Wet-only Two-weekly

Precipitation amount, official gauge

Sulphate DK05, DK08, DK12, DK22 Wet-only Two-weekly Ion chromatography

Nitrate DK05, DK08, DK12, DK22 Wet-only Two-weekly Ion chromatography

Ammonium DK05, DK08, DK12, DK22 Wet-only Two-weekly ISO 11732 CFA (continuously flow analysis) and

spectrophotometric detection

Magnesium DK05, DK08, DK12, DK22 Wet-only Two-weekly Ion chromatography

Sodium DK05, DK08, DK12, DK22 Wet-only Two-weekly Ion chromatography

Chloride DK05, DK08, DK12, DK22 Wet-only Two-weekly Ion chromatography

Calcium DK05, DK08, DK12, DK22 Wet-only Two-weekly Ion chromatography

Potassium DK05, DK08, DK12, DK22 Wet-only Two-weekly Ion chromatography

Conductivity

pH DK05, DK08, DK12, DK22 Wet-only Two-weekly pH meter

Air

Sulphur dioxide DK03, DK08, DK12, DK31 KOH-impregnated Whatman 41 filters, 58 m

/day Daily Ion chromatography

Nitrogen dioxide DK05, DK08, DK12, DK31 Monitor Hourly Chemiluminescence

Nitrogen oxide DK05, DK08, DK12, DK31 Monitor Hourly Chemiluminescence

Nitric acid

Ammonia DK03, DK08, DK12, DK31

Oxalic acid impregnated Whatman 41, 58 m

/day Daily ISO 11732 CFA (continuously flow analysis) and spectrophotometric detection

Ozone DK05, DK12, DK31 UV-monitor Hourly UV-absorption

Sulphate DK03, DK05, DK08, DK31 Millipore RAWP 1.2 mm, 58 m

/day Daily Ion chromatography

Nitrate

Ammonium DK03, DK08, DK12, DK31

Millipore RAWP 1.2 mm, 58 m

/day Daily ISO 11732 CFA (continuously flow analysis) and spectrophotometric detection

Sodium DK03, DK08, DK12, DK31 Millipore RAWP 1.2 mm, 58 m

/day Daily Ion chromatography

Calcium DK03, DK08, DK12, DK31 Millipore RAWP 1.2 mm, 58 m

/day Daily Ion chromatography

Magnesium DK03, DK08, DK12, DK31 Millipore RAWP 1.2 mm, 58 m

/day Daily Ion chromatography

Potassium DK03, DK08, DK12, DK31 Millipore RAWP 1.2 mm, 58 m

/day Daily Ion chromatography

Chloride DK03, DK08, DK12, DK31 Millipore RAWP 1.2 mm, 58 m

/day Daily Ion chromatography

PM

DK05, DK12 Low volume sampling Daily Gravimetric

PM

2.5