Chapter 2: Equipment in Shock Tube Testing Facility
2.2 Specification of the Equipment
2.2.1 Compressed air cylinder
O presente estudo mostrou que um modelo de regressão de segunda ordem foi adequado para descrever e prever o rendimento em percentual de óleo dentro das faixas experimentais avaliadas, tendo permitido a obtenção de superfícies de respostas e definir as regiões de interesse para o processo.
134
Os fatores temperatura, teor de água dos grãos, tamanho de partículas, tempo de extração e interação entre teor de água e tamanho de partículas influenciaram significativamente o rendimento em óleo extraído. O rendimento do processo aumenta com o aumento da temperatura e do tempo e com a diminuição do teor de água e tamanho médio das partículas.
As condições necessárias para a obtenção do máximo rendimento em percentual de óleo extraído foram: temperatura igual a 68,8 °C, teor de água igual a 0 %, tamanho de partículas igual ou inferior a 0,5 mm e tempo igual a 120 min. Para estas condições, o rendimento em percentual de óleo extraído foi estimado em 73,8 % em relação ao teor de óleo total dos grãos.
O processo de extração por imersão utilizando etanol como solvente se mostrou adequado para a extração de óleo de pinhão-manso, principalmente para partículas de tamanho inferior a 1 mm e com teor de água de até 2 % b.u..
6.5 LITERATURA CITADA
ABRAHAM, G.; HRON, R. J.; KUK, M. S.; WAN, P. J. Water accumulation in the alcohol extraction of cottonseed. Journal of the American Oil Chemists Society, v.70, p.207-210, 1993.
BECKER, W. Solvent extraction of soybean. Journal of American Oil Chemists’
Society, v.55, p.754–761, 1978.
BHATTACHARJEE, P., SINGHAL, R.S., TIWARI, S.R. Supercritical carbon dioxide extraction of cottonseed oil. Journal of Food Engineering. v,79, p.892–898, 2007. BOX, G. E. P.; WILSON, K. B. Experimental attainment of optimum conditions.
Journal of the Royal Statistical Society, v.13, p.1-45, 1951.
BOX, G. E. P.; WETZ, J. Criteria for judging adequacy of estimation by an approximate response function. University of Wisconsin, Tecological Report, n.9, 1993.
CARVALHO, L. C. C. Álcool do Brasil: energia limpa e renovável. Agro Analysis, v.21, n.9, 2001.
CHIERICE, G. O.; CLARO NETO, S. Aplicação industrial do óleo. In: AZEVEDO, D. M. P.; LIMA, E. F. O agronegócio da mamona no Brasil. Campina Grande: Embrapa Algodão / Brasília: Embrapa Informação Tecnológica, p. 89-120, 2001.
DANH, L.T.; MAMMUCARIA, R.; TRUONG, P.; FOSTER, N. Response surface method applied to supercritical carbon dioxide extraction of Vetiveria zizanioides essential oil. Chemical Engineering Journal, v.155, p.617-626, 2009.
135
DOMINGOS, K. A., SAAD, E. B., WILHELM, H. M., RAMOS, L. P. Optimization of the ethanolysis of Raphanus sativus (L. Var.) crude oil applying the response surface methodology. Bioresource Technology, v.99, p.1837-1845, 2008.
FRANCO, D.; SINEIRO, J.; PINELO, M.; NÚÑEZ, M. J. Ethanolic extraction of Rosa rubiginosa soluble substances: Oil solubility equilibria and kinetic studies. Journal of
Food Engeneering, v.79, p.150-157, 2007.
GANDHI, A. P., JOSHI, K. C. JHA, K., PARIHAR, V. S. SRIVASTAV, D.C., RAGHUNADH, P., KAWALKAR, J., JAIN S. K., TRIPATHI, R. N., Studies on alternative solvents for the extraction of oil-I soybean. International Journal of Food
Science and Technology, v.38, p.369-375, 2003.
GUBITZ, G.; MITTELBACH, M.; TRABI, M. Exploitation of the tropical oil seed plant Jatropha curcas L. Bioresource Technology. v.67, p.73-82, 1999.
INSTITUTO ADOLFO LUTZ. Normas analíticas do Instituto Adolfo Lutz. 3ª edição, São Paulo: Instituto Adolfo Lutz, 1985. 533p.
JEONG, G.; YANG, H.; PARK, D. Optimization of transesterification of animal fat ester using response surface methodology. Bioresource Technology, v.100, p. 25–30, 2009.
JOHNSON, L. A.; LUSAS, E. W. Comparison of alternative solvents for oils extraction
Journal of American Oil Chemists’ Society. v.60, p.229-242, 1983.
KAPARTHI, R.; CHARI, K. S. Solubilities of vegetable oils in aqueous ethanol and ethanol-hexane mixtures. Journal of American Oil Chemists’ Society. v.36, p.77-80, 1959.
KARNOFSKY, G. Ethanol and isopropanol as solvents for full-fat cottonseed extraction. Oil Mill Gazette. v.85, n.10, p.34-36, 1981.
LIAUW, M. Y.; NATAN, F. A.; WIDIYANTI, P.; IKASARI, D.; INDRASWATI, N.; SOETAREDJO, F. E. Extraction of neem oil (Azadirachta indica A. Juss) using n- hexane and ethanol: studies of oil quality, kinetic and thermodynamic. Journal of
Engineering and Applied Sciences, v.3, n.3, 2008.
LIN, J.; YANG, F.; TANG, L.; CHEN, F. Antitumor effects of curcin from seeds of Jatropha curcas. Acta Pharmacologica Sinica. v.24, n.3, p.241-246, 2003.
LUSAS, E. W.; WATKINS, L. R.; KOSEOGLU, S. S. Isopropyl alcohol to be tested as solvent. INFORM, v.2, n.11, p.972-973, 1991.
MACHMUDAH, S., KAWAHITO, Y., SASAKI, M., GOTO, M. Supercritical CO2
extraction of rosehip seed oil: fatty acids composition and process optimization.
Journal of Supercritical Fluids, v.41, p.421–428, 2007.
MAGNE, F. C., SKAU, E. L. Phase equilibrium data pertaining to the extraction of cottonseed oil with ethanol and 2-propanol. Journal of American Oil Chemists’
136
MANI S, JAYA S, VADIVAMBAL R. Optimization of solvent extraction of Moringa (Moringa oleifera) seed kernel oil using response surface methodology. Trans
IChemE, Part C, Food and Bioproducts Processing, v.85, n4, p.328-335, 2007.
MARTÍNEZ-HERRERA, J.; SIDDHURAJUB, P.; FRANCISB,G.; DÁVILA-ORTÍZA, G.; BECKERB, K. Chemical composition, toxic/antimetabolic constituents, and effects of different treatments on their levels, in four provenances of Jatropha curcas L. from Mexico. Food Chemistry, v.96, n.1, p.80-89, 2006.
MEZIANE, S.; KADI, H.; LAMROUS, O. Kinetic study of oil extraction from olive foot cake. Grasas y Aceites, v.57, p.175-179, 2006.
MEZIANE, S.; KADI, H. Kinetics and thermodynamics of oil extraction from olive cake. Journal of the American Oil Chemists’ Society, v.85, n.4, p.391−396, 2008. MONTGOMERY, D. C. Design and analysis of experiments (5th ed.). New York: Wiley, 2001, p. 455-92.
NARAIN, M.; SINGH, B. P. N. Characteristics of solvent extraction plant and machinery being made in India. In: Proceedings 2° National Seminar on Soybean Processing and Utilization, 1988, Pantnagar, India, 1988.
PEREZ, E. E.; CARELLI, A. A.; CRAPISTE, G. H. Temperature-dependent diffusion coefficient of oil from different sunflower seeds during extraction with hexane. Journal
of Food Engineering, v.105, n.1, p.180–185, 2011.
RAO, R. K.; KRISHNA, M. G.; ZAHEER, S. M.; ARNOLD, L. K. Alcoholic extraction of vegetable oils: I. Solubilities of cottonseed, peanut, sesame, and soybean oils in aqueous ethanol. Journal of American Oil Chemists’ Society. v.32, p.420-423, 1955.
RODRIGUES, M. I.; IEMMA, A. F. Planejamento de experimentos. 1ª ed. Campinas: 2005, 326p.
SAYYAR, S.; ABIDIN, Z. Z.; YUNUS, R.; MUHAMMAD, A. Extraction of oil from Jatropha seeds-optimization and kinetics. American Journal Applied Science, v.6, n.7, p.1390–1395, 2009.
SILVA, M. T. C.; TURATTI, J. M. Extração de óleo de soja com etanol. Coletânea do
ITAL, v.21, n.1, p.73-89, 1991.
TIWARI A. K; KUMAR, A.; RAHEMAN, H. Biodiesel production from Jatropha oil (Jatropha curcas L.) with high free fatty acids: an optimized process. Biomass &
Bioenergy, v.31, p.569-75, 2007.
VICENTE, G.; MARTÍNEZ, M.; ARACIL, J. Optimization of integrated biodiesel production. Part I: a study of the biodiesel purity and yield. Bioresource Technology, v.98, p.1724-1733, 2007a.
VICENTE, G.; MARTÍNEZ, M.; ARACIL, J. Optimization of integrated biodiesel production. Part II: A study of the material balance. Bioresource Technology, v.98, p. 1754-1761, 2007b.
137