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FID*100 (ug/cm2) Temp/100 laser/1000

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thermal protocol with a maximum temperature in He of 650 °C (a), He-750 (b) and He-850 (c) protocols. The LAC-only samples were generated, as a mixture of pyrolysed organic carbon and native EC, by thermal treatment of PM2.5 ambient aerosol samples according to the method proposed by Yu and Li (19).

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FID*100 (ug/cm2) Temp/100 laser/1000

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He He/O2

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Figure S3.1a

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FID Response; Temperature (degree)

FID*100 (ug/cm2) Temp/100 laser/1000

He He/O2

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FID*100 (ug/cm2) Temp/100 laser/1000

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