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Sponge-like porous manganese(II,III) oxide as a highly efficient cathode material for rechargeable magnesium ion batteries

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Electronic Supplementary Information (ESI)

Sponge-like Porous Manganese(II,III) Oxide as a Highly Efficient Cathode Material for Rechargeable Magnesium

Ion Batteries

Lu Wang1, Karina Asheim1, Per Erik Vullum2, Ann Mari Svensson1 and Fride Vullum-Bruer1,*

1 Department of Materials Science and Engineering, NTNU, Norwegian University of Science and Technology, NO-7491 Trondheim, Norway

2 SINTEF Materials and Chemistry, NO-7491 Trondheim, Norway

* Corresponding Authors. E-mail: [email protected]

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Figure S1. Typical cyclic voltammograms of Mg deposition-stripping in 0.4 M APC electrolyte. Experiments are conducted on a coin cell, at a scan rate of 10 mV s-1 and room temperature with Mg metal as reference- and counter electrode. The inset shows the enlargement of the area between 2.1 and 3V.

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Figure S2. The photographs of a dissembled coin cell after 1000 cycles charge/discharge.

The cell was washed by THF in order to clean the residual electrolyte and dried 2 hours at room temperature under vacuum.

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Figure S3. Cyclic stability of pure Gif cycled at 20 mA g-1.

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Figure S4. CV curve of U-Mn3O4 at the scan rate of 0.2 mV s-1 compared with pure Gif.

The inset shows the CV curve of Gif.

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